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1

Stereoselective Nucleophilic Fluoromethylation of Aryl Ketones: Dynamic Kinetic Resolution of Chiral α-Fluoro Carbanions

Shen, Xiao, Miao, Wenjun, Ni, Chuanfa, Hu, Jinbo

Journal:

Angewandte Chemie International Edition

Year:

2014

Language:

english

File:

PDF, 475 KB

english, 2014

2

Good Partnership between Sulfur and Fluorine: Sulfur-Based Fluorination and Fluoroalkylation Reagents for Organic Synthesis

Ni, Chuanfa, Hu, Mingyou, Hu, Jinbo

Journal:

Chemical Reviews

Year:

2015

Language:

english

File:

PDF, 16.17 MB

english, 2015

3

Correlation Between Diabetic Peripheral Neuropathy and Sarcopenia in Patients with Type 2 Diabetes Mellitus and Diabetic Foot Disease: A Cross-Sectional Study

Yang, Qin, Zhang, Yingxiao, Zeng, Qinglian, Yang, Chan, Shi, Jiale, Zhang, Chunlin, Ni, Xia, Du, Zhipeng, Tang, Ziwei, Hu, Jinbo, Li, Xuemei, Cai, Jiahui, Li, Qifu, Cheng, Qingfeng

Journal:

Diabetes Metabolic Syndrome and Obesity Targets and Therapy

Year:

2020

Language:

english

File:

PDF, 436 KB

english, 2020

4

gem -Difluoroolefination of Diaryl Ketones and Enolizable Aldehydes with Difluoromethyl 2-Pyridyl Sulfone: New Insights into the Julia-Kocienski Reaction

Gao, Bing, Zhao, Yanchuan, Hu, Mingyou, Ni, Chuanfa, Hu, Jinbo

Journal:

Chemistry - A European Journal

Year:

2014

Language:

english

File:

PDF, 583 KB

english, 2014

5

Chemically oxidative fluorination with fluoride ions

Ni, Chuanfa, Jiang, Fanzhou, Zeng, Yuwen, Hu, Jinbo

Journal:

Journal of Fluorine Chemistry

Year:

2015

Language:

english

File:

PDF, 2.63 MB

english, 2015

6

Copper-Mediated Aromatic 1,1-Difluoroethylation with (1,1-Difluoroethyl)trimethylsilane (TMSCF 2 CH 3 )

Li, Xinjin, Zhao, Jingwei, Wang, Yunze, Rong, Jian, Hu, Mingyou, Chen, Dingben, Xiao, Pan, Ni, Chuanfa, Wang, Limin, Hu, Jinbo

Journal:

Chemistry – An Asian Journal

Year:

2016

Language:

english

File:

PDF, 401 KB

english, 2016

7

A Remarkably Efficient Fluoroalkylation of Cyclic Sulfates and Sulfamidates with PhSO2CF2H: Facile Entry into β-Difluoromethylated or β-Difluoromethylenated Alcohols and Amines

Chuanfa Ni, Jun Liu, Laijun Zhang, Jinbo Hu

Journal:

Angewandte Chemie International Edition

Year:

2007

Language:

english

File:

PDF, 135 KB

english, 2007

8

From Difluoromethyl 2-Pyridyl Sulfone to Difluorinated Sulfonates: A Protocol for Nucleophilic Difluoro(sulfonato)methylation

Prof. Dr. G. K. Surya Prakash, Dr. Chuanfa Ni, Fang Wang, Prof. Dr. Jinbo Hu, Prof. Dr. George A. Olah

Journal:

Angewandte Chemie International Edition

Year:

2011

Language:

english

File:

PDF, 320 KB

english, 2011

9

Nucleophilic (phenylsulfinyl)difluoromethylation of carbonyl compounds with difluoromethyl phenyl sulfoxide

Lingui Zhu, Ya Li, Chuanfa Ni, Jinbo Hu, Petr Beier, Ying Wang, G.K. Surya Prakash, George A. Olah

Journal:

Journal of Fluorine Chemistry

Year:

2007

Language:

english

File:

PDF, 330 KB

english, 2007

10

Nucleophilic difluoromethylation of carbonyl compounds using TMSCF2SO2Ph and Mg0-mediated desulfonylation

Chuanfa Ni, Jinbo Hu

Journal:

Tetrahedron Letters

Year:

2005

Language:

english

File:

PDF, 114 KB

english, 2005

11

Facile preparation of difluoromethyl- and monofluoromethyl-containing amides via Ritter reaction

Jun Liu, Chuanfa Ni, Ya Li, Laijun Zhang, Guanyu Wang, Jinbo Hu

Journal:

Tetrahedron Letters

Year:

2006

Language:

english

File:

PDF, 124 KB

english, 2006

12

Palladium/acetic acid-catalyzed fluoroalkylation of alkynes with monofluorinated sulfones as pronucleophiles

Chuanfa Ni, Jinbo Hu

Journal:

Tetrahedron Letters

Year:

2009

Language:

english

File:

PDF, 420 KB

english, 2009

13

Stereoselective Nucleophilic Monofluoromethylation of N-(tert-Butanesulfinyl)imines with Fluoromethyl Phenyl Sulfone

Li, Ya, Ni, Chuanfa, Liu, Jun, Zhang, Laijun, Zheng, Ji, Zhu, Lingui, Hu, Jinbo

Journal:

Organic Letters

Year:

2006

Language:

english

File:

PDF, 106 KB

english, 2006

14

Stereoselective synthesis of α-difluoromethyl-β-amino alcohols via nucleophilic difluoromethylation with Me3SiCF2SO2Ph

Jun Liu, Chuanfa Ni, Fang Wang, Jinbo Hu

Journal:

Tetrahedron Letters

Year:

2008

Language:

english

File:

PDF, 194 KB

english, 2008

15

Nucleophilic Fluoroalkylation of α,β-Enones, Arynes, and Activated Alkynes with Fluorinated Sulfones: Probing the Hard/Soft Nature of Fluorinated Carbanions

Ni, Chuanfa, Zhang, Laijun, Hu, Jinbo

Journal:

Journal of Organic Chemistry

Year:

2008

Language:

english

File:

PDF, 649 KB

english, 2008

16

Copper-Mediated Trifluoromethylation of α-Diazo Esters with TMSCF 3 : The Important Role of Water as a Promoter

Hu, Mingyou, Ni, Chuanfa, Hu, Jinbo

Journal:

Journal of the American Chemical Society

Year:

2012

Language:

english

File:

PDF, 318 KB

english, 2012

17

Tuning the Reactivity of Difluoromethyl Sulfoximines from Electrophilic to Nucleophilic: Stereoselective Nucleophilic Difluoromethylation of Aryl Ketones

Shen, Xiao, Zhang, Wei, Ni, Chuanfa, Gu, Yucheng, Hu, Jinbo

Journal:

Journal of the American Chemical Society

Year:

2012

Language:

english

File:

PDF, 293 KB

english, 2012

18

Nucleophilic difluoromethylation of CN bonds in heterocycles with difluoromethyl silane reagents

Weizhou Huang, Chuanfa Ni, Yanchuan Zhao, Wei Zhang, Alexander D. Dilman, Jinbo Hu

Journal:

Year:

2012

Language:

english

File:

PDF, 4.81 MB

english, 2012

19

Synthesis of Fluorinated β-Ketosulfones and gem -Disulfones by Nucleophilic Fluoroalkylation of Esters and Sulfinates with Di- and Monofluoromethyl Sulfones

Ni, Chuanfa, Zhang, Laijun, Hu, Jinbo

Journal:

Journal of Organic Chemistry

Year:

2009

Language:

english

File:

PDF, 231 KB

english, 2009

20

Copper-Mediated Fluoroalkylation of Aryl Iodides Enables Facile Access to Diverse Fluorinated Compounds: The Important Role of the (2-Pyridyl)sulfonyl Group

Zhao, Yanchuan, Gao, Bing, Ni, Chuanfa, Hu, Jinbo

Journal:

Organic Letters

Year:

2012

Language:

english

File:

PDF, 478 KB

english, 2012

21

Nucleophilic difluoromethylation of N,N-acetals with TMSCF2SO2Ph reagent promoted by trifluoroacetic acid: A facile access to α-difluoromethylated tertiary amines

Weizhou Huang, Chuanfa Ni, Yanchuan Zhao, Bing Gao, Jinbo Hu

Journal:

Journal of Fluorine Chemistry

Year:

2012

Language:

english

File:

PDF, 965 KB

english, 2012

22

Silver-Mediated Trifluoromethylation–Iodination of Arynes

Zeng, Yuwen, Zhang, Laijun, Zhao, Yanchuan, Ni, Chuanfa, Zhao, Jingwei, Hu, Jinbo

Journal:

Journal of the American Chemical Society

Year:

2013

Language:

english

File:

PDF, 461 KB

english, 2013

23

Nucleophilic Fluoroalkylation of α , β -Unsaturated Carbonyl Compounds with α -Fluorinated Sulfones: Investigation of the Reversibility of 1,2-Additions and the Formation of 1,4-Adducts

Shen, Xiao, Ni, Chuanfa, Hu, Jinbo

Journal:

Helvetica Chimica Acta

Year:

2012

Language:

english

File:

PDF, 270 KB

english, 2012

24

Copper-Catalyzed Debenzoylative Monofluoromethylation of Aryl Iodides Assisted by the Removable (2-Pyridyl)sulfonyl Group

Zhao, Yanchuan, Ni, Chuanfa, Jiang, Fanzhou, Gao, Bing, Shen, Xiao, Hu, Jinbo

Journal:

Year:

2013

Language:

english

File:

PDF, 702 KB

english, 2013

25

Nucleophilic difluoro(phenylsulfonyl)methylation of carbonyls with PhSO2CF2H reagent in the presence of in situ generated substoichiometric amount of base

Hu, Mingyou, Gao, Bing, Ni, Chuanfa, Zhang, Laijun, Hu, Jinbo

Journal:

Journal of Fluorine Chemistry

Year:

2013

Language:

english

File:

PDF, 1.67 MB

english, 2013

26

Copper-mediated trifluoromethylation of propiolic acids: facile synthesis of α-trifluoromethyl ketones

He, Zhengbiao, Zhang, Rui, Hu, Mingyou, Li, Lingchun, Ni, Chuanfa, Hu, Jinbo

Journal:

Chemical Science

Year:

2013

Language:

english

File:

PDF, 275 KB

english, 2013

27

Nucleophilic Fluoroalkylation of Epoxides with Fluorinated Sulfones

Ni, Chuanfa, Li, Ya, Hu, Jinbo

Journal:

Journal of Organic Chemistry

Year:

2006

Language:

english

File:

PDF, 117 KB

english, 2006

28

Highly Stereoselective and One-Pot Synthesis of Tetra-substituted Monofluoroalkenes with Aldehydes and Fluorobis(phenylsulfonyl)methane

Shen, Xiao, Ni, Chuanfa, Hu, Jinbo

Journal:

Chinese Journal of Chemistry

Year:

2013

Language:

english

File:

PDF, 568 KB

english, 2013

29

Synthesis of gem -Difluorocyclopropa(e)nes and O - , S - , N - , and P-Difluoromethylated Compounds with TMSCF 2 Br

Li, Lingchun, Wang, Fei, Ni, Chuanfa, Hu, Jinbo

Journal:

Angewandte Chemie International Edition

Year:

2013

Language:

english

File:

PDF, 605 KB

english, 2013

30

Copper-Catalyzed gem -Difluoroolefination of Diazo Compounds with TMSCF 3 via C–F Bond Cleavage

Hu, Mingyou, He, Zhengbiao, Gao, Bing, Li, Lingchun, Ni, Chuanfa, Hu, Jinbo

Journal:

Journal of the American Chemical Society

Year:

2013

Language:

english

File:

PDF, 647 KB

english, 2013

31

AgF-Mediated Fluorinative Homocoupling of gem -Difluoroalkenes

Gao, Bing, Zhao, Yanchuan, Ni, Chuanfa, Hu, Jinbo

Journal:

Organic Letters

Year:

2014

Language:

english

File:

PDF, 522 KB

english, 2014

32

Palladium-catalyzed allylation of 2,2,2-trifluoroethyl phenyl sulfone, a potential 2,2,2-trifluoroethyl pronucleophile

Zhang, Wei, Zhao, Yanchuan, Ni, Chuanfa, Mathew, Thomas, Hu, Jinbo

Journal:

Tetrahedron Letters

Year:

2012

Language:

english

File:

PDF, 1.82 MB

english, 2012

33

Copper-Mediated Trifluoromethylthiolation of α-Diazoesters

Hu, Mingyou, Rong, Jian, Miao, Wenjun, Ni, Chuanfa, Han, Yongxin, Hu, Jinbo

Journal:

Organic Letters

Year:

2014

Language:

english

File:

PDF, 444 KB

english, 2014

34

Stereoselective [3+2] cycloaddition of N-tert-butanesulfinyl imines to arynes facilitated by a removable PhSO 2 CF 2 group: synthesis and transformation of cyclic sulfoximines

Ye, Wenchao, Zhang, Laijun, Ni, Chuanfa, Rong, Jian, Hu, Jinbo

Journal:

Chemical Communications

Year:

2014

Language:

english

File:

PDF, 1.66 MB

english, 2014

35

Nucleophilic Difluoro(phenylsulfonimidoyl)methylation of Unactivated Alkyl Bromides with PhSO(NTBS)CF 2 H: Facile Entry into gem -Difluoroalkenes

Shen, Xiao, Liu, Qinghe, Ni, Chuanfa, Hu, Jinbo

Journal:

Chinese Journal of Chemistry

Year:

2014

Language:

english

File:

PDF, 375 KB

english, 2014

36

Nucleophilic Fluoroalkylation of Epoxides with Fluorinated Sulfones

Ni, Chuanfa, Li, Ya, Hu, Jinbo

Journal:

Journal of Organic Chemistry

Year:

2008

Language:

english

File:

PDF, 122 KB

english, 2008

37

Radical (2-pyridylsulfonyl)difluoromethylation of terminal alkenes with iododifluoromethyl 2-pyridyl sulfone

Miao, Wenjun, Ni, Chuanfa, Zhao, Yanchuan, Hu, Jinbo

Journal:

Journal of Fluorine Chemistry

Year:

2014

Language:

english

File:

PDF, 540 KB

english, 2014

38

Copper(0)-mediated fluoroalkylation of iodobenzene with 2-bromo-1,1,2,2-tetrafluoroethyl compounds: Investigation on the influence of R substituent on the reactivity of RCF2Cu species

Zhu, Jieming, Ni, Chuanfa, Gao, Bing, Hu, Jinbo

Journal:

Journal of Fluorine Chemistry

Year:

2015

Language:

english

File:

PDF, 2.61 MB

english, 2015

39

Fluoroalkylative Aryl Migration of Conjugated N -Arylsulfonylated Amides Using Easily Accessible Sodium Di- and Monofluoroalkanesulfinates

He, Zhengbiao, Tan, Ping, Ni, Chuanfa, Hu, Jinbo

Journal:

Organic Letters

Year:

2015

Language:

english

File:

PDF, 822 KB

english, 2015

40

Palladium-Catalyzed Monofluoromethylation of Arylboronic Esters with Fluoromethyl Iodide

Hu, Jingyu, Gao, Bing, Li, Lingchun, Ni, Chuanfa, Hu, Jinbo

Journal:

Organic Letters

Year:

2015

Language:

english

File:

PDF, 516 KB

english, 2015

41

Selective Nucleophilic Fluoroalkylations Facilitated by Removable Activation Groups

Ni, Chuanfa, Hu, Jinbo

Journal:

Year:

2011

Language:

english

File:

PDF, 261 KB

english, 2011

42

gem-Difluoroolefination of Diazo Compounds with TMSCF3 or TMSCF2Br: Transition-Metal-Free Cross-Coupling of Two Carbene Precursors

Hu, Mingyou, Ni, Chuanfa, Li, Lingchun, Han, Yongxin, Hu, Jinbo

Journal:

Journal of the American Chemical Society

Year:

2015

Language:

english

File:

PDF, 1.25 MB

english, 2015

43

Copper-Mediated Aerobic (Phenylsulfonyl)difluoromethylation of Arylboronic Acids with Difluoromethyl Phenyl Sulfone

Li, Xinjin, Zhao, Jing-Wei, Hu, Mingyou, Chen, Dingben, Ni, Chuanfa, Wang, Limin, Hu, Jinbo

Journal:

Chemical Communications

Year:

2016

Language:

english

File:

PDF, 1.42 MB

english, 2016

44

Nucleophilic Iododifluoromethylation of Carbonyl Compounds Using Difluoromethyl 2-Pyridyl Sulfone

Miao, Wenjun, Ni, Chuanfa, Zhao, Yanchuan, Hu, Jinbo

Journal:

Organic Letters

Year:

2016

Language:

english

File:

PDF, 855 KB

english, 2016

45

Radical Fluoroalkylation of Isocyanides with Fluorinated Sulfones by Visible-Light Photoredox Catalysis

Rong, Jian, Deng, Ling, Tan, Ping, Ni, Chuanfa, Gu, Yucheng, Hu, Jinbo

Journal:

Angewandte Chemie International Edition

Year:

2016

Language:

english

File:

PDF, 793 KB

english, 2016

46

Recent Advances in the One-Step Synthesis of Distally Fluorinated Ketones

Zeng, Yuwen, Ni, Chuanfa, Hu, Jinbo

Journal:

Chemistry - A European Journal

Year:

2016

Language:

english

File:

PDF, 5.36 MB

english, 2016

47

Copper-Mediated Deuterotrifluoromethylation of α ?Diazo Esters

Hu, Mingyou, Xie, Qiqiang, Li, Xinjin, Ni, Chuanfa, Hu, Jinbo

Journal:

Chinese Journal of Chemistry

Year:

2016

Language:

english

File:

PDF, 322 KB

english, 2016

48

O -Trifluoromethylation of Phenols: Access to Aryl Trifluoromethyl Ethers by O -Carboxydifluoromethylation and Decarboxylative Fluorination

Zhou, Min, Ni, Chuanfa, He, Zhengbiao, Hu, Jinbo

Journal:

Organic Letters

Year:

2016

Language:

english

File:

PDF, 715 KB

english, 2016

49

The unique fluorine effects in organic reactions: recent facts and insights into fluoroalkylations

Ni, Chuanfa, Hu, Jinbo

Journal:

Chemical Society Reviews

Year:

2016

Language:

english

File:

PDF, 5.82 MB

english, 2016

50

Bis(difluoromethyl)trimethylsilicate Anion: A Key Intermediate in Nucleophilic Difluoromethylation of Enolizable Ketones with Me 3 SiCF 2 H

Chen, Dingben, Ni, Chuanfa, Zhao, Yanchuan, Cai, Xian, Li, Xinjin, Xiao, Pan, Hu, Jinbo

Journal:

Angewandte Chemie International Edition

Year:

2016

Language:

english

File:

PDF, 965 KB

english, 2016